Organosilicon Compounds II
نویسندگان
چکیده
منابع مشابه
Some highly sterically hindered organosilicon compounds
The chemistry of organometallic compounds with bulky ligands such as (Me3Si)3C(Tsi) or (Me2PhSI)3C(Tpsi) attached to a variety of metal centres is reviewed. The compounds Tsi2M (M = Zn, Cd, Hg) and the rare two co-ordinate TsiMn show exceptional thermal and hydrolytic stability. The corresponding alkylmetal halides form ring or cage structures. In a range of new boron compounds the structures o...
متن کاملCarbonfunctional Organosilicon Compounds: Synthesis of Some Silylcoumarins
C a r b o n f u n c t i o n a l s i l a n e s b e a r i n g c o u m a r i n t y p e f u n c t i o n a l g r o u p s a r e o f i n t e r e s t d u e t o t h e i r p o t e n t i a l i m p o r t a n c e as p r e c u r s o r s i n c o s m e t i c i n d u s t r i e s . W e r e p o r t t h e s y n t h e s i s o f s o m e 4 o r g a n o s i l i c o n d e r i v a t i v e s o f 7 h y d r o x y c o u m a ...
متن کاملSynthesis and Radioprotective Activity of New Organosilicon and Germanium Compounds
Silathiazolidine and metalladithioacetals (M = Si, Ge) have been prepared by the interaction of dialkyldichloro- or bis(diethylamino)dialkylsilanes and -germanes with 3-[N-(2- thioethyl)]amino-propanamide (WR-2529) and [1-thioethyl-2-(1-naphtylmethyl)]-2- imidazoline. The study of these compounds in the field of chemical radioprotection has shown a notable decrease in the toxicity and a rather ...
متن کاملContemporary organosilicon chemistry
Editorial for the Thematic Series on Contemporary Organosilicon Chemistry.
متن کاملRegio- and stereoselective functionalization of electron-deficient alkenes by organosilicon compounds via photoinduced electron transfer*
Regioand stereoselective photoallylation of electron-deficient alkenes by use of allylic silanes via photoinduced electron transfer has been described. Similar photoinduced functionalization reactions such as arylmethylation, alkylation, and silylation can be achieved by using a variety of organosilicon compounds. These photoreactions proceed via radical cations of organosilicon compounds and r...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Nippon kagaku zassi
سال: 1950
ISSN: 0369-5387,2185-0917
DOI: 10.1246/nikkashi1948.71.350